Concentrating on Chromatography

Episode 78: SPME, PFAS & Green Chemistry with Dr. Emanuela Gionfriddo

September 14, 2026·33 min
Episode Description from the Publisher

Dr. Emanuela Gionfriddo, Associate Professor of Chemistry at the University at Buffalo, joins host David Oliva to explore solid phase microextraction (SPME), green analytical chemistry, and PFAS analysis. Trained in Professor Janusz Pawliszyn's lab at the University of Waterloo — where SPME was invented — she shares how deep SPME theory reshaped her research and now drives her lab's work on environmental and biological chemistry.In this episode, Emanuela discusses how SPME complies with the 12 principles of green analytical chemistry, why her lab consistently produces the least waste in her department, and how biomimetic SPME devices using natural biopolymers like alginic acid and chitin reveal how pollutants bioaccumulate in the environment. She also covers her lab's PFAS research, including a surprising study testing mascara for PFAS contamination, the analytical challenges of volatile PFAS detection, and why field-deployable PFAS quantification isn't quite ready yet.Topics covered: SPME fundamentals, green analytical chemistry, PFAS detection, biomimetic extraction, mixed-mode sorbents, GC×GC for volatile PFAS, and emerging microplastics research.Connect with Dr. Emanuela Gionfriddo: https://www.linkedin.com/in/emanuela-gionfriddo-60492659/Subscribe to Concentrating on Chromatography for more conversations with leading separation science researchers.

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